Journal of the American Chemical Society

Silyl radicals. VII. Novel intramolecular aryl migrations from carbon to silicon by a free-radical mechanism. Migration vs. cyclization

H Sakurai, A Hosomi

文献索引：Journal of the American Chemical Society, , vol. 92, p. 7507 - 7508

全文：HTML全文

被引用次数: 22

摘要

... These results now suggest the following mechanism (Chart I) for the competition of rearrangement us. cyclization of 1 involving a spirocyclohexadienyl radical (4) as an intermediate. ... Journal of the American Chemical Society 1 92:25 1 December 16, 1970