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Chemical Communications

A metal complex that imitates a micelle

N Giri, SL James

文献索引:Giri, Nicola; James, Stuart L. Chemical Communications, 2011 , vol. 47, # 1 p. 245 - 247

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被引用次数: 8

摘要

The concept of 'metal-complex-as-amphiphile', in which metal complexes act as components of metallo-micelles, is well established. 1,2 However, an alternative concept, that of 'metal-complex-as-micelle', in which a single metal complex imitates the structure and behaviour of a complete micelle, has not yet been described. Here we report an example of such a metal complex. The structure is shown generically in Fig. 1a, and can be seen as a hybrid of a ...