Tetrahedron

Palladium-catalyzed acylation and/or homo-coupling of aryl-and alkyl-acetylenes

S Perrone, F Bona, L Troisi

文献索引：Perrone, Serena; Bona, Fabio; Troisi, Luigino Tetrahedron, 2011 , vol. 67, # 38 p. 7386 - 7391

全文：HTML全文

被引用次数: 23

摘要

Allyl or benzyl halides, through a Pd (0)-catalyzed reaction and under CO pressure, generate acyl-palladium/halides that, in the presence of a base and an aryl-and alkyl- acetylene, undergo nucleophilic acyl substitution giving conjugated acetylenic ketones. Diynes, resulting from alkyne/alkyne homo-coupling, were instead the main products in reactions performed without allyl or benzyl halides. Moreover, dimerization, trimerization, ...