Palladium-catalyzed cross-carbonylation of aryl iodides with five-membered cyclic olefins

…, T Itaya, K Okuro, M Miura, M Nomura

文献索引：Satoh, Tetsuya; Itaya, Tomoaki; Okuro, Kazumi; Miura, Masahiro; Nomura, Masakatsu Journal of Organic Chemistry, 1995 , vol. 60, # 22 p. 7267 - 7271

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被引用次数: 38

摘要

Intermolecular cross-carbonylation of aryl iodides with five-membered cyclic olefins such as dihydrofurans and cyclopentene was found to proceed by using a catalyst system of PdClflPh3 under CO (3-5 atm) in the presence of a tertiary amine. With 2, 3-and 2, 5- dihydrofurans, 2-aroyl-4, 5-dihydro-and 3-aroyl-2, 3-dihydrofans were obtained as the predominant products, respectively, while the reaction of iodobenzene with cyclopentene ...