Sulfur chelates. 31. Synthesis and characterization of aryl xanthogens, xanthate esters, and esters of O-aryl S-alkyl thiocarbonates. Synthesis and single-crystal x-ray …
HW Chen, JP Fackler Jr, DP Schussler…
文献索引：Chen,H.W. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 2370 - 2375
Abstract: The synthesis and characterization of aryl xanthogens are reported in this paper. These materials are readily formed by oxidation of the metal aryl xanthates.', 2 Attempts to prepare the analogous COS derivatives by a similar route failed, although esters of the 0- aryl thiocarbonates were obtained by a less direct route. The reaction of the aryl xanthogens with CuCl leads to the formation of a copper (1) complex in which the thione sulfur atom of ...
