Positional isomeric and N-donor auxiliary chelating ligand effect on engineering crystalline architectures of four lead (II) complexes with diverse fluorescent properties
This work presents an investigation on the positions of the substituent and N-donor auxiliary chelating ligand (bipy/phen) effect on engineering of crystalline architectures of four Pb (II) complexes with a pair of methyl-substituted 3-sulfobenzoic isomers:[Pb (4- msba)(phen)(H2O)](1),[Pb (4-msba)(bipy)(H2O)]· H2O (2),[Pb (5-msba)(phen) 2]· 9H2O (3), and [Pb2 (5-msba) 2 (bipy) 2 (H2O) 2](4)(4/5-msba= 4/5-methyl-3-sulfobenzoate, phen= 1, ...