Structures of tetrasilylmethane derivatives (XMe2Si) 2C (SiMe3) 2 (X= H, Cl, Br) in the gas phase, and their dynamic structures in solution

DA Wann, MS Robinson, K Bätz…

文献索引：Ayoko, G. Adefikayo; Eaborn, Colin Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1047 - 1058

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摘要

... The Journal of Physical ... Chemical shifts of all NMR spectra are reported in ppm relative to TMS. ... T. R is the gas constant, while ΔG i and g i are the Gibbs free energy difference (with respect to the lowest energy conformer) and degeneracy, respectively, of state i, where g i is ...