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Tetrahedron

Fused carbazoles by tandem aza Wittig/electrocyclic ring closure. Preparation of 6H-pyrido [4, 3-b] carbazole, 11H-pyrido [4, 3-a] carbazole and 11H-pyrido [3, 4-a] …

P Molina, PM Fresneda, P Almendros

文献索引:Molina, Pedro; Fresneda, Pilar M.; Almendros, Pedro Tetrahedron, 1993 ,  vol. 49,  # 6  p. 1223 - 1236

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被引用次数: 32

摘要

Aza Wittig type reaction of iminophosphoranes 3, 12 and 16, prepared from the appropriate formylcarbazole by sequential treatment with ethyl azidoacetate and triphenylphosphine, with isocyanates leads to the linear 6H-pyrido [4, 3-b] carbazole 5, the angular 11H-pyrido [4, 3-a] carbazole 13 and the isomeric 11H-pyrido [3, 4-a] carbazole 19 respectively.