Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

…, M Gembicky, M Messerschmidt, P Coppens

文献索引：Zhang, Jing; Gembicky, Milan; Messerschmidt, Marc; Coppens, Philip Chemical Communications, 2007 , # 23 p. 2399 - 2401

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被引用次数: 1

摘要

Intermolecular H-bonding between CO (ketone) and HO (4′-hydroxyphenyl) quenches photodecarbonylation of 2, 2, 4, 4-tetramethyl-1, 3-di (4′-hydroxyphenyl) acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4, 4′-bicyclohexanone.