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The Journal of Organic Chemistry

New synthetic approach to 4-alkylidenecyclohexenes. Reduction-protodesilylation of benzylsilanes

DJ Coughlin, RG Salomon

文献索引:Coughlin,D.J.; Salomon,R.G. Journal of Organic Chemistry, 1979 , vol. 44, p. 3784 - 3790

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被引用次数: 38

摘要

Results Synthesis of Benzylsilanes. A representative selection of primary, secondary, and tertiary benzylsilanes was prepared by replacement of a benzylic halogen or hydrogen with a trimethylsilyl group by several methods. Thus benzylsilanes 5a-e (Table I) were prepared by in situ