Three new ways to synthesize 1, 3-azoles derivatives on mineral supports using Ca (OCl) 2Al 2O 3 or MnO 2SiO 2 or by fusion “in dry media” are described. The reactions are activated under microwave irradiation in a monomode Synthewave 402 reactor. The reaction times are considerably shortened and the products are obtained in higher yields and better purity, than compared to conventional heating.