文献索引：McMahon, Terrance B.; Heinis, Thomas; Nicol, Gordon; Hovey, Jamey K.; Kebarle, Paul Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7591 - 7598
Abstract: Measurement of the CH3+(Me') transfer equilibria, B'Me'+ B= B'+ MeB+, with a pulsed high-pressure mass spectrometer and an ion cyclotron resonance mass spectrometer led to a scale of relative methyl cation affinities of bases B, MCA (B). This scale when calibrated to the literature value for the Me+ affinity of N2 led to absolute MCA values for the other 24 bases B that were part of the scale. Rate constants for several Me+ ...
