Synthesis

Stereoselective synthesis and reactivity of dienyl zirconocene derivatives

N Chinkov, S Majumdar, I Marek

文献索引：Chinkov, Nicka; Majumdar, Swapan; Marek, Ilan Synthesis, 2004 , # 14 p. 2411 - 2417

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被引用次数: 4

摘要

Abstract Stereoselective dienyl zirconocene derivatives have been prepared via a tandem allylic CH bond activation isomerization-elimination reaction. These reagents can be either trapped directly with electrophiles or transmetalated to copper to participate in several carbon-carbon bond formations. When the transmetalation is performed on allylic as well as vinylic zirconocene derivatives, the reaction occurs with inversion of stereochemistry of the ...