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The mechanism of base-induced gas-phase elimination reactions of thioethers

WW Van Berkel, LJ De Koning…

文献索引:Berkel, Werefridus W. van; Koning, Leo J. de; Nibbering, Nico M. M. Journal of the American Chemical Society, 1987 , vol. 109, # 25 p. 7602 - 7608

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被引用次数: 17

摘要

2. The [C2H40]'+ ions formed from ethylene oxide have stable structure d, although a fraction isomerize to structure f and g, during collisions with the gaseous or metal target. It is not possible to exclude the presence of some ions with structure c in the stable ion beam. 3. [CzH40]'+ ions derived from 1,3-dioxolane and ethylene oxide are identical with those from ethylene carbonate. There is no evidence for a contribution from structure b in the I ,3-di- oxolane ...