Synthesis

Complementary Reactions of Allylic Carbamates Using Palladium (II): Formation of Oxazolidinones or Allylic Amides from a Common Precursor

SDR Christie, AD Warrington, CJ Lunniss

文献索引：Christie, Steven D. R.; Warrington, Adam D.; Lunniss, Christopher J. Synthesis, 2009 , # 1 p. 148 - 154

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摘要

Abstract The use of palladium to effect two different reactions on a common starting material is presented. With a copper oxidant, an aminohalogenation is achieved to produce oxazolidinones. When the copper is absent, a [3, 3]-sigmatropic rearrangement takes place to produce allylic amides.