Reactions of polyfluoroaryl bromides and iodides with c−, si−, ge−, sn−, and pb-electrophiles and tris (dialkylamino) phospines [1]

…, LS Pressman, LN Rogoza, GG Furin

文献索引：Bardin, V. V.; Pressman, L. S.; Rogoza, L. N.; Furin, G. G. Journal of Fluorine Chemistry, 1991 , vol. 53, # 2 p. 213 - 231

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被引用次数: 18

摘要

Abstract The reactions of polyfluoroaryl bromides Ar F Br or iodides Ar FI with P (NR′ 2) 3 and R 3 MX (R= alkyl; M= Si, Ge, Sn, and Pb; X= Cl, Br) led to the formation of Ar F MR 3. The reactions of C 6 F 5 Br with P (Net 2) 3 and C-electrophiles (CH 3 I, C 6 F 5 CF 3 and (CF 3) 2 C= CFC 2 F 5) gave the products of pentafluorophenylation of these substrates.