General method for the synthesis of 1, 3-dienes. Simple syntheses of. beta.-and trans-. alpha.-farnescene from farnesol

S Tanaka, A Yasuda, H Yamamoto…

文献索引：Tanaka,S. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 3252 - 3254

全文：HTML全文

被引用次数: 50

摘要

Sir: A highly stereospecific transformation of allylic alcohols into ethylenic derivatives has previously been described, as has the application of this reaction to the stereospecific synthesis of CIS Cecropia juvenile hormone.'The process is convenient and depending on the choice of reagent allows the synthesis of either olefinic isomer in good yields with high stereospecificity. We now wish to report a general method for an allylic alcohol-1, 3-diene ...