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Tetrahedron letters

Selenoesters in organic synthesis. 1. A novel synthesis of ketones.

…, MS Ermolenko, DV Yashunsky, NK Kochetkov

文献索引:Sviridov, A.F.; Ermolenko, M.S.; Yashunsky, D.V.; Kochetkov, N.K. Tetrahedron Letters, 1983 , vol. 24, # 40 p. 4355 - 4358

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被引用次数: 43

摘要

During the realization of synthetic programme directed to macrolide antibiotics construction we needed in mild and efficient ester to ketone transformation. Traditional sequence including ester cleavage, preparation of active acyl-transfer derivative followed by reaction with appropriate organometallics have some dis&antages for natural products synthesis since may affect position& to carboxylic group. Therefore we are interested in more mild ...