Asymmetric allylic alkylation of acyclic allylic ethers with organolithium reagents

…, M Fañanás??Mastral, V Hornillos…

文献索引：Perez, Manuel; Fananas-Mastral, Martin; Hornillos, Valentin; Rudolph, Alena; Bos, Pieter H.; Harutyunyan, Syuzanna R.; Feringa, Ben L. Chemistry - A European Journal, 2012 , vol. 18, # 38 p. 11880 - 11883

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被引用次数: 14

摘要

Asymmetric allylic substitution is one of the most powerful synthetic transformations with numerous applications in the total synthesis of biologically active compounds and natural products.[1] The use of metal complexes such as Pd,[2] Mo [3], or Ir [4] in combination with mainly allylic carbonates or acetates represents an excellent methodology for the use of stabilized nucleophiles in this transformation. On the other hand, Cu-catalyzed asymmetric ...