Absorption spectra and photochemical rearrangements of 1-, 2-, and 3-chlorocycloheptatriene and 7-chloronorbornadiene cations in solid argon
L Andrews, CK Payne, BJ Kelsall…
文献索引：Andrews, Lester; Kelsall, Benuel J.; Payne, Christopher K.; Rodig, Oscar R.; Schwarz, Helmut Journal of Physical Chemistry, 1982 , vol. 86, p. 3714 - 3721
Matrix photoionization of chlorocycloheptatriene (CCHT) during condensation with excess argon at 20 K produced new broad 484-, 517-, and 544-nm bands, a sharp 469.3-nm absorption, and weak 453-and 468-nm bands. The broad bands are assigned to the 1-, 2-, and 3-chlorocycloheptatriene cations. Photolysis with 500-1000-nm radiation decreased the broad bands and increased the sharp 469.3-nm absorption. The 469.3-nm band and a ...
