The Preparation of Some Unsymmetrical Organotin Bromides and Acetates

SD Rosenberg, E Debreczeni…

文献索引：Rosenberg, S. D.; Debreczeni, E.; Weinberg, E. L. Journal of the American Chemical Society, 1959 , vol. 81, p. 972 - 975

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被引用次数: 34

摘要

A series of unsymmetrical organotin bromides has been prepared by the stepwise cleavage of appropriate organotin compounds with bromine in carbon tetrachloride or chloroform at- 50, O or 40'. The bromides have been converted to acetates by treatment with aqueous potassium hydroxide to form bisorganotin oxides, followed by reaction of these intermediate conipounds with glacial acetic acid at 100'.