Synthetic Communications

Synthesis of 1-Formyl 1, 1-Dialkylmethylphosphonates

MP Teulade, P Savignac

文献索引：Teulade, Marie-Paule; Savignac, Philippe Synthetic Communications, 1987 , vol. 17, # 2 p. 125 - 136

全文：HTML全文

被引用次数: 8

摘要

Abstract Preparation of 1-formyl 1, 1-dialkylmethylphosphonates is described. A carbanionic route is provided by the condensation of α-lithio α, α-disubstituted methylphosphonates with ethylformate whereas a carbocationic route provided by the acid catalyzed rearrangement of β, β-disubstituted epoxyethylphosphonates is re-evaluated.