The Journal of Organic Chemistry

The chemistry of carbanions. 29. The nature of the enolate formed by addition of lithium dimethylcuprate to enones

HO House, JM Wilkins

文献索引：House,H.O.; Wilkins,J.M. Journal of Organic Chemistry, 1976 , vol. 41, # 25 p. 4031 - 4033

全文：HTML全文

被引用次数: 35

摘要

4-Methoxy-2-methylthio-N-methylthiobenzamide(8). A solution of 1.36 g (7.5 mmol) of thioamide IC in 20 ml of dry THF was cooled in an ice bath under N2. Then 10 ml (l6 mmol) of a 1.6 m solution of n-BuLi in hexane was added dropwise and stirred for 8.5 h at room temperature. The reaction mixture was recooled in an ice bath and 800 mg (8.5 nimol) of methyl disulfide added. The mixture was stirred at 25" C for 18 h, quenched with water, ...