Organometallics

Room-Temperature Selective Aliphatic Carbon–Carbon Bond Activation and Functionalization of Ethers by Rhodium (II) Porphyrin

SY Lee, TH Lai, KS Choi, KS Chan

文献索引：Lee, Siu Yin; Lai, Tsz Ho; Choi, Kwong Shing; Chan, Kin Shing Organometallics, 2011 , vol. 30, # 14 p. 3691 - 3693

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被引用次数: 10

摘要

Selective aliphatic carbon (α)–carbon (β) bond activation of ethers by (5, 10, 15, 20- tetramesitylporphyrinato) rhodium (II)(Rh (tmp)(1)) was achieved at room temperature to yield corresponding rhodium porphyrin alkyls and the functionalized esters. Rh (tmp) OH was the proposed intermediate responsible for cleaving the C (α)–C (β) bond. The reaction is general for both straight-and branch-chain ethers.