Amido-derivatives of metals and metalloids. Part X. Reactions of titanium (IV), zirconium (IV), and hafnium (IV) amides with unsaturated substrates, and some related …
G Chandra, AD Jenkins, MF Lappert…
文献索引：Chandra,G. et al. Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1970 , p. 2550 - 2558
Insertion reactions of amides LM–(NR2) n with the dipoles AB to give the adducts LM (NR2) n–x (A–B–NR2) x are described. The amides included the Group IVA [M (NMe2) 4 (M= Ti, Zr, or Hf)] and IVB [Me3M· NMe2 (M= Si, Ge, or Sn)] compounds and o-C6H4O2B· NEt2, while the dipoles were PhNCO, PhNCS, MeNCS, p-MeC6H4· N: C: N· C6H4Me-p, C6H11· N: C: N· C6H11, MeO2C· C: C· CO2Me, CO2, CS2, CH2: CH· CN, PhCN, p-MeC6H4· CN, CH2: ...
