Chemical physics

Structures and its dipole moments of half-sandwich type metal–benzene (1: 1) complexes determined by 2-m long electrostatic hexapole

K Imura, H Ohoyama, T Kasai

文献索引：Imura, Kohei; Ohoyama, Hiroshi; Kasai, Toshio Chemical Physics, 2004 , vol. 301, # 2-3 p. 183 - 187

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被引用次数: 16

摘要

The transition metal–benzene (1: 1) complexes are synthesized by laser evaporation method followed by the size and structure selection with 2-m long electrostatic hexapole field. Electric dipole moments of half-sandwich type binary complexes for a series of the transition metals, ie Ti, V, Co, and Ni, with benzene molecule were determined by measuring the focusing curves, namely the dependence of the focused beam intensity upon the ...