The Journal of Organic Chemistry

Enol and acyl phosphates as intermediates in the synthesis of nonrandom triglycerides

JE Thompson

文献索引：Thompson,J.E. Journal of Organic Chemistry, 1965 , vol. 30, p. 4276 - 4280

全文：HTML全文

被引用次数: 7

摘要

Trialkyl phosphites and dialkyl bromomalonates have been reported to react at 0'to give enol phosphates or at 150” to give phosphonomalonates. However, examination of infrared and nmr spectra of trialkyl phosphitedialkyl bromomalonate reaction products has failed to provide any evidence of phosphonomalonate formation. Instead, enol phosphates are produced at both temperatures. Fatty acyl phosphates, which can be prepared from the ...