Biogenetically inspired stereospecific synthesis of the dienylvinylcyclopropane gamete attractant dictyopterene B

WD Abraham, T Cohen

文献索引：Abraham, William D.; Cohen, Theodore Journal of the American Chemical Society, 1991 , vol. 113, # 6 p. 2313 - 2314

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被引用次数: 25

摘要

Although cis, cis-undeca-1, 5, 8-trien-3-01 (the Z, Z isomer of 7) has been proposed as a biosynthetic precursor of the marine gamete attractants dictyopterene B (lo), dictyopterene D (13), and the two CIIH16 tetraenes 11 and 12,'~~ 7 has never been converted to these gamete attractants. We now disclose that such conversions can be executed in a highly efficient and stereospecific manner, especially with regard to the formation of 10. 7 (mainly ...