Chemistry Letters

Novel Catalysis in the Internal Nanocavity of Polyamine Dendrimer for Intramolecular Michael Reaction

…, T Mitsudome, T Mizugaki, K Jitsukawa, K Kaneda

文献索引：Maeno, Zen; Mitsudome, Takato; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Chemistry Letters, 2012 , vol. 41, # 8 p. 801 - 803

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被引用次数: 4

摘要

Poly (propyleneimine)(PPI) dendrimers functionalized with C 16 alkyl chains acted as efficient tertiary amine catalysts for an intramolecular Michael reaction. The substrate was accommodated in a reactive conformation within a sterically confined nanocavity consisting of regularly arranged tertiary amino groups of the PPI dendrimers.