Thermal reactions of hexafluorobutadiene and hexafluorocyclobutene with elemental sulphur

…, EI Mysov, AF Aerov, EM Kagramanova

文献索引：Kazmina, N. B.; Mysov, E. I.; Aerov, A. F.; Kagramanova, E. M. Journal of Fluorine Chemistry, 1993 , vol. 65, # 3 p. 203 - 208

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被引用次数: 1

摘要

Abstract Hexafluorobuta-1, 3-diene and hexafluorocyclobutene interact with elemental sulphur under conditions of mutual conversion (⩾ 280 C) to give the same products, hexafluoro-3, 6-dihydro-1, 2-dithiine (1), hexafluorothiolene-3 (2) and hexafluorothiolanethione (3). The product composition and ratio depend on the reaction conditions. Dithiine 1 and thiolene 2 were formed in competitive reactions. Their thermal ...