Structures of lithium salts of 2, 3, 3-trimethylindolenine and its 5-methoxy derivative in solution and the solid state
LM Jackman, LM Scarmoutzos, BD Smith…
文献索引：Jackman, L. M.; Scarmoutzos, L. M.; Smith, B. D.; Williard, Paul G. Journal of the American Chemical Society, 1988 , vol. 110, # 18 p. 6058 - 6063
Abstract: An X-ray crystal structure of lithium 2, 3, 3-trimethylindolenide etherate shows it to be a disolvated dimer having a 7)-azaallyl-type structure. The structures of the salt in several solvents have been established by studies of I3C chemical shifts, 6Li, 15N spinspin splitting, 7Li quadrupole splitting constants, and apparent degrees of aggregation determined by vapor pressure barometry. It is the? 3-azaallyl dimer disolvate in diethyl ether, a ...
