Journal of Organometallic Chemistry

Reaction of group iv hydrides with fluoroacetylenes

WR Cullen, GE Styan

文献索引：Cullen,W.R.; Styan,G.E. Journal of Organometallic Chemistry, 1966 , vol. 6, p. 117 - 125

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被引用次数: 5

摘要

Abstract Hexafluoro-2-butyne reacts easily with the tin hydrides R 3 SnH (R= alkyl) to give mainly trans-R 3 SnC (CF 3) C (CF 3) H. The dihydride,(nC 4 H 9) 2 SnH 2, reacts similarly.(CH 3) 3 SiH and (C 2 H 5) 3 GeH add to the butyne on UV irradiation. In the case of the silane a 1: 2 adduct,(CH 3) 3 SiCHCF 3 CHCF 3 Si (CH 3) 3, is also produced. Heating (CH 3) 3 SiH and CF 3 C CCF 3 yields both 1: 1 and 1: 2 adducts.(CH 3) 3 SnH ...