η3-Furfuryl and η3-thienyl complexes of palladium and platinum of relevance to the functionalization of biomass-derived furans

…, P Brenner, S Bertsch, K Radacki, RD Dewhurst

文献索引：Shi, Yang; Brenner, Peter; Bertsch, Stefanie; Radacki, Krzysztof; Dewhurst, Rian D. Organometallics, 2012 , vol. 31, # 15 p. 5599 - 5605

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被引用次数: 7

摘要

A number of cationic and neutral η3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated ...