Fluorescent polyolefins by free radical post-reactor modification with functional nitroxides

…, S Coiai, C Pinzino, F Ciardelli, E Passaglia

文献索引：Cicogna, Francesca; Coiai, Serena; Pinzino, Calogero; Ciardelli, Francesco; Passaglia, Elisa Reactive and Functional Polymers, 2012 , vol. 72, # 10 p. 695 - 702,8

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被引用次数: 16

摘要

The 4-(1-naphthoate)-2, 2, 6, 6-tetramethylpiperidine-1-oxyl (NfO-TEMPO) has been synthesized and successfully grafted in the melt onto a random poly (ethylene-co-1-ottene) copolymer. Functionalized polyolefins have been prepared by coupling reaction between NfO-TEMPO free radicals and macroradicals which have been formed by H-abstraction induced by the presence of a peroxide. In order to deepen insight into the functionalization ...