Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium] 2 [cis-MoO2 (salicylato-O1, O2) 2]
K Boutilier, LR MacGillivray, S Subramanian…
文献索引：Boutilier, Kelly; MacGillivray, Leonard R.; Subramanian, S.; Zaworotko, Michael J. Journal of Crystallographic and Spectroscopic Research, 1993 , vol. 23, # 10 p. 773 - 778
Abstract The complex salt,[1-MeimH] 2 [cis-MoO 2 (sal) 2], 1,(1-Meim= 1-methylimidazole, sal= oC 6 H 4 (C−)(COC−)) has been prepared by reacting Mo (CO) 6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P¯ 1, a= 9.220 (2), b= 9.469 (3), c= 15.368 (4) Å, α= 105.04 (4), β= 99.48 (3), γ= 109.48 (3)°, Z= 2, D calc= 1.60 g/cm. 2809 reflections with I ...
