Electrochemical and spectroscopic studies of 3, 5-di-tert-butyl-2-aminophenol and of electrosynthesized 3, 5-di-tert-butyl-2-iminocyclohexa-3, 5-dienone in aprotic …
SP Harmalker, DT Sawyer
文献索引：Harmalker, Subhash P.; Sawyer, Donald T. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3579 - 3583
In acetonitrile 3, 5-di-tert-butyl-2-iminocyclohexa-3, 5-dienone (DTBQI) is the major product from the controlled-potential electrooxidation of 3, 5-di-tert-butyl-2-aminophenol (DTBAPH2). The same product results from the chemical oxidation of DTBAPHz by PbO2. The redox chemistry for DTBAPH2, DTBQI, and o-aminophenol in dimethyl sulfoxide and acetonitrile has been studied with cyclic voltammetry and controlledpotential electrolysis, and the ...
