Journal of Fluorine Chemistry

Synthesis of β-fluoroalkyl phenyl (or methyl) thioethers by sulfur-assisted halogen exchange with triethylamine tris-hydrofluoride

C Saluzzo, G Alvernhe, D Anker, G Haufe

文献索引：Saluzzo, C.; Alvernhe, G.; Anker, D.; Haufe, G. Journal of Fluorine Chemistry, 1990 , vol. 47, # 3 p. 467 - 479

全文：HTML全文

被引用次数: 11

摘要

Abstract The exchange of chlorine in β-chloroalkyl phenyl (or methyl) thioethers by fluorine, with anchimeric assistance of sulfur, is very easily realized with the almost neutral fluorinating reagent, Et 3 N. 3HF. The 'one-pot'reactions of alkenes with sulfenyl chlorides and subsequently with Et 3 N. 3HF lead to the corresponding β-fluoroalkyl thioethers in high yields.