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Tetrahedron

Transition-metal catalyzed silylzincation and silylalumination of acetylenic compounds

K Wakamatsu, T Nonaka, Y Okuda, W Tückmantel…

文献索引:Wakamatsu, Kuni; Nonaka, Tsuyoshi; Okuda, Yasuhiro; Tueckmantel, Werner; Oshima, Koichiro; et al. Tetrahedron, 1986 , vol. 42, # 16 p. 4427 - 4436

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被引用次数: 51

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Dialkyl(dimethylphenylsilyl)zinclithium and trialkyl(dimethylphenylsilyl)aluminiumlithium add effectively to internal acetylenes as well as terminal ones in the presence of transition-metal catalysts to provide vinylsilanes with high stereo- and regioselectivities.