Inorganica chimica acta

Synthesis and reactivity of the bulky germanium (IV) trisamide complexes BrGe [N (SiMe 3) 2] 3 and LiGe [N (SiMe 3) 2] 3: X-ray crystal structures of BrGe [N (SiMe 3) 2 …

JL Walding, PE Fanwick, CS Weinert

文献索引：Walding, Jennifer L.; Fanwick, Phillip E.; Weinert, Charles S. Inorganica Chimica Acta, 2005 , vol. 358, # 4 p. 1186 - 1192

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被引用次数: 7

摘要

The bulky germanium (IV) trisamide complex BrGe [N (SiMe3) 2] 3 has been prepared and structurally characterized. Reaction of this material with nBuLi resulted in [(Me3Si) 2N] 3Ge (CH2CH2CH2CH3), which has also been structurally characterized, but no reaction with lithium metal was observed in the attempted preparation of LiGe [N (SiMe3) 2] 3. However, analytically pure LiGe [N (SiMe3) 2] 3was prepared by the reaction of 3 equivalents of LiN ...