UPE studies of conjugation involving Group 5A elements. 1. Phenylphosphines

DE Cabelli, AH Cowley, MJS Dewar

文献索引：Cabelli, Diane E.; Cowley, Alan H.; Dewar, Michael J. S. Journal of the American Chemical Society, 1981 , vol. 103, # 12 p. 3286 - 3289

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被引用次数: 30

摘要

Abstract: UPE spectra are reported for phenylphosphine, p-phenylenediphosphine, phenyldichlorophosphine, p-phenylenebis (dichlorophosphine), phenylbis (diethylamino) phosphine, and p-phenylenebis (diethy1amino) diphosphine. Analysis using PMO theory indicates that the assignments in phenylphosphine and aniline are similar, ZI in each case corresponding to ionization from a perturbed benzene T MO, I3 to a perturbed lone pair. ...