Gold??Catalyzed Intermolecular C S Bond Formation: Efficient Synthesis of α??Substituted Vinyl Sulfones

…, TL Gregg, NG Akhmedov, JL Petersen…

文献索引：Xi, Yumeng; Dong, Boliang; McClain, Edward J.; Wang, Qiaoyi; Gregg, Tesia L.; Akhmedov, Novruz G.; Petersen, Jeffrey L.; Shi, Xiaodong Angewandte Chemie - International Edition, 2014 , vol. 53, # 18 p. 4657 - 4661 Angew. Chem., 2014 , vol. 126, # 18 p. 4745 - 4749,5

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被引用次数: 44

摘要

Abstract A general method for the synthesis of α-substituted vinyl sulfones makes use of a combination of a triazole gold complex and gallium triflate. This efficient C [BOND] S bond formation between simple terminal alkynes and sulfinic acids provides access to various α- substituted vinyl sulfones.