Synthesis and nuclear magnetic resonance spectra of some substituted vinyldiphenylphosphines

SO Grim, RP Molenda, JD Mitchell

文献索引：Grim,S.O.; Molenda,R.P. Journal of Organic Chemistry, 1980 , vol. 45, p. 250

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被引用次数: 45

摘要

Some substituted vinyl tertiary phosphines have been synthesized by the reaction of the substituted vinyl Grignard reagents with (C&,) 2PCl and C6H $ C12. The compounds include (C6H5), PC (CH3)= CH2,(2)-and (E)-(C&5) 2PCH= CHCH,,(C&&PCH= C (CHJ2,(2)-and (E)- (C6HS) 2PC (CH3)= CHCH3, and the compound mixture@', E)-,(Z, Z)-, and (EB)-(c, H,) P (cH= CHcH,),. 31P and'H NMR data are reported. Those phosphines which have a methyl ...