Organometallics

Dimesitylsilyl derivatives of zirconium

DM Roddick, RH Heyn, TD Tilley

文献索引：Roddick, Dean M.; Heyn, Richard H.; Don Tilley, T. Organometallics, 1989 , vol. 8, p. 324 - 330

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被引用次数: 78

摘要

Dean M. Roddick, Richard H. Heyn, and T. Don Tilley" ... Chemistry Department, 0-006, University of California, San Diego, La Jolla, California 92093 ... The preparation and characterization of (THF)zLiSiHMesz (1, Mes = mesityl) are reported. Compound 1 reacts with Cp,Zr(Me)Cl (Cp = q5-C5H5) to afford thermally unstable Cp,Zr(SiHMes )Me (2), characterized ... Introduction The development of early-transition-metal silicon chemistry has been hampered by a lack ...