Tetrahedron

The reaction of nitriles with O, O-dialkyldithiophosphoric acids

NM Yousif

文献索引：Yousif, N. M. Tetrahedron, 1989 , vol. 45, # 14 p. 4599 - 4604

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被引用次数: 17

摘要

Nitriles react with dialkyldithiophosphoric acids 2 ac to give a mixture of corresponding thioamides and O, O-dialkyl-N-thioaceyl-phosphoroamidothioates 3 ae. The structure of compounds 3 are elucidated chemically and from electronic spectra. The yield of thioamides are improved from the reaction of nitriles with compound 2 b in presence of water. Mechanistic consideration on the formation of the products are discussed.