Poly (ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer

…, P le Maux, C Paul, J Rault-Berthelot…

文献索引：Poriel, Cyril; Ferrand, Yann; Le Maux, Paul; Paul, Christine; Rault-Berthelot, Joelle; Simonneaux, Gerard Chemical Communications, 2003 , # 18 p. 2308 - 2309

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被引用次数: 32

摘要

Oxidative electropolymerization of tetraspirobifluorenyl porphyrin ruthenium (II) carbonyl complexes can be used to coat Pt electrodes with polymeric films; after being removed from the electrode, these polymeric materials are able to catalyze the heterogeneous cyclopropanations and 2, 3 sigmatropic rearrangements with ethyl diazoacetate.