Synthesis and conversion reactions of alkenyl-and hydride siloxanes

KA Andrianov, VI Sidorov, LM Khananashvili

文献索引：Andrianov,K.A. et al. Journal of Organometallic Chemistry, 1965 , vol. 4, p. 360 - 370

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被引用次数: 5

摘要

Abstract The reactions of organosiloxanes containing the vinyl group in the α-and β- positions, with diazomethane and phenyl azide have been studied. It is concluded that siloxanes containing the vinyl group in the α-position react with diazomethane and phenyl azide but not siloxanes with the vinyl group in the β-position. The 1-pyrazolin-3-yl derivatives of organosiloxanes formed decompose when heated yielding the corresponding allyl ...