Palladium-catalyzed addition of mono-and dicarbonyl compounds to conjugated dienes

…, J Larsen, C Steffens, JF Hartwig

文献索引：Leitner, Andreas; Larsen, Jens; Steffens, Christian; Hartwig, John F. Journal of Organic Chemistry, 2004 , vol. 69, # 22 p. 7552 - 7557

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被引用次数: 43

摘要

An intermolecular, palladium-catalyzed addition of the α-CH bond of monocarbonyl and 1, 3- dicarbonyl compounds to dienes has been developed, and an exploration of the scope of these reactions with a broad range of carbonyl compounds and nitriles was conducted. The combination of CpPd (allyl) and the commercially available 1, 3-bis (dicyclohexylphosphino) propane (DCyPP) catalyzed the 1: 1 addition of the CH bonds of these substrates to ...