Journal of the American Chemical Society

Bis heteroannulation. 1. Model studies in the synthesis of highly oxygenated sesquiterpenes

PA Jacobi, T Craig

文献索引：Jacobi,P.A.; Craig,T. Journal of the American Chemical Society, 1978 , vol. 100, p. 7748 - 7750

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被引用次数: 27

摘要

3 4, 5(4) position of butene predominated, as is usual for a-allylpalladium complexes. Pent-1- ene and hex-1-ene reacted similarly, giving mixtures of olefin isomers, although the reaction was slower and less efficient than with propene. Surprisingly, cyclopentene, cycldhexene, and allylbenzene failed to produce allylic alkylation products under these reaction conditions. x-Allylpalladium chloride or PdCI*(CH3CN) 2 were the best sources of ...