Dioxygen-coupled oxidative amination of styrene

VI Timokhin, NR Anastasi, SS Stahl

文献索引：Timokhin, Vitaliy I.; Anastasi, Natia R.; Stahl, Shannon S. Journal of the American Chemical Society, 2003 , vol. 125, # 43 p. 12996 - 12997

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被引用次数: 119

摘要

Dioxygen-coupled oxidative amination of olefins is an attractive, but challenging, catalytic transformation. The present work describes the first general method for intermolecular oxidative amination of aryl olefins with molecular oxygen as the stoichiometric oxidant. This palladium-catalyzed reactivity is compatible with several different nitrogen nucleophiles, including oxazolidinone, phthalimide, pyrrolidinone, and p-toluenesulfonamide. The ...