(Phenylalkyl) palladium Complexes Containing β??Hydrogen Atoms: Synthesis and Characterization of [PdR2 (dppe)],[PdR (SPh)(dppe)](R= CH2CH2Ph, …

…, C Wagner, K Merzweiler, D Steinborn

文献索引：Spaniel, Thomas; Schmidt, Harry; Wagner, Christoph; Merzweiler, Kurt; Steinborn, Dirk European Journal of Inorganic Chemistry, 2002 , # 11 p. 2868 - 2877

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被引用次数: 7

摘要

Abstract Reactions of HgR 2 (R= CH 2 CH 2 Ph, 1a; CH 2 CH 2 CH 2 Ph, 1b; CH 2 CHMePh, 1c)(prepared from HgCl 2 and the requisite Grignard compounds) with lithium in toluene afforded (phenylalkyl) lithium compounds LiR (2a− c) in yields of between 64 and 81%. At− 30 C, they react with [PdCl 2 (dppe)][dppe= 1, 2-bis (diphenylphosphanyl) ethane] yielding bis (phenylalkyl) palladium (II) complexes [PdR 2 (dppe)](3a− c) which were isolated (T ...